Tudóstér: Kálmán Ferenc publikációi

Arató, V., Képes, Z., Péli-Szabó, J., Farkasinszky, G., Sass, T., Dénes, N., Kis, A., Opposits, G., Jószai, I., Kálmán, F., Hajdu, I., Trencsényi, G., Kertész, I.: Acute Myelomonoblastic Leukemia (My1/De): a Preclinical Rat Model.
In Vivo. 38 (3), 1064-1073, 2024.

Képes, Z., Hegedűs, É., Sass, T., Csikos, C., Péli-Szabó, J., Szugyiczki, V., Hajdu, I., Kertész, I., Opposits, G., Imrek, J., Balkay, L., Kálmán, F., Trencsényi, G.: Concomitant [18F]F-FAZA and [18F]F-FDG Imaging of Gynecological Cancer Xenografts: insight Into Tumor Hypoxia.
In Vivo. 38 (2), 574-586, 2024.

Bunda, S., Kálmán-Szabó, I., Lihi, N., Képes, Z., Szikra, D., Péli-Szabó, J., Timári, I., Szűcs, D., May, N., Papp, G., Trencsényi, G., Kálmán, F.: Diagnosis of Melanoma with 61Cu-Labeled PET Tracer.
J. Med. Chem. [Epub ahead of print]2024.

Kálmán-Szabó, I., Bunda, S., Lihi, N., Szaniszló, Z., Szikra, D., Péli-Szabó, J., Fekete, A., Gyuricza, B., Szücs, D., Papp, G., Trencsényi, G., Kálmán, F.: 61Cu-Labelled radiodiagnostics of melanoma with NAPamide-targeted radiopharmaceutical.
Int. J. Pharm. 632 1-9, 2023.

Bunda, S., Lihi, N., Szaniszló, Z., Esteban-Gómez, D., Platas-Iglesias, C., Kéri, M., Papp, G., Kálmán, F.: Bipyridil-based chelators for Gd(III) complexation: kinetic, structural and relaxation properties.
Dalton Trans. 52 (45), 17030-17040, 2023.

Laczovics, A., Csige, I., Szabó, S., Tóth, A., Kálmán, F., Tóth, I., Fülöp, Z., Berényi, E., Braun, M.: Relationship between gadolinium-based MRI contrast agent consumption and anthropogenic gadolinium in the influent of a wastewater treatment plant.
Sci. Total Environ. 877 1-8, 2023.

Csupász, T., Szücs, D., Kálmán, F., Hollóczki, O., Fekete, A., Szikra, D., Tóth, É., Tóth, I., Tircsó, G.: A New Oxygen Containing Pyclen-Type Ligand as a Manganese(II) Binder for MRI and 52Mn PET Applications: Equilibrium, Kinetic, Relaxometric, Structural and Radiochemical Studies.
Molecules. 27 1-27, 2022.

Csupász, T., Lihi, N., Fekete, Z., Nagy, A., Botár, R., Forgács, V., Szikra, D., May, N., Tircsó, G., Kálmán, F.: Exceptionally fast formation of stable rigidified cross-bridged complexes formed with Cu(II) isotopes for Molecular Imaging.
Inorg. Chem. Front. 9 (6), 1217-1223, 2022.

Váradi, B., Lihi, N., Bunda, S., Nagy, A., Simon, G., Kéri, M., Papp, G., Tircsó, G., Esteban-Gómez, D., Platas-Iglesias, C., Kálmán, F.: Physico-Chemical Characterization of a Highly Rigid Gd(III) Complex Formed with a Phenanthroline Derivative Ligand.
Inorg. Chem. 61 (34), 13497-13509, 2022.

Lucio-Martínez, F., Garda, Z., Váradi, B., Kálmán, F., Esteban-Gómez, D., Tóth, É., Tircsó, G., Platas-Iglesias, C.: Rigidified Derivative of the Non-macrocyclic Ligand H4OCTAPA for Stable Lanthanide(III) Complexation.
Inorg. Chem. 61 (12), 5157-5171, 2022.

Botár, R., Molnár, E., Garda, Z., Madarasi, E., Trencsényi, G., Kiss, J., Kálmán, F., Tircsó, G.: Synthesis and characterization of a stable and inert Mn-II-based Zn-II responsive MRI probe for molecular imaging of glucose stimulated zinc secretion (GSZS).
Inorg. Chem. Front. 9 (3), 577-583, 2022.

Garda, Z., Molnár, E., Hamon, N., Barriada, J., Esteban-Gómez, D., Váradi, B., Nagy, V., Póta, K., Kálmán, F., Tóth, I., Lihi, N., Platas-Iglesias, C., Tóth, É., Tripier, R., Tircsó, G.: Complexation of Mn(II) by Rigid Pyclen Diacetates: Equilibrium, Kinetic, Relaxometric, Density Functional Theory, and Superoxide Dismutase Activity Studies.
Inorg. Chem. 60 (2), 1133-1148, 2021.

Garda, Z., Kócs, T., Bányai, I., Martins, J., Kálmán, F., Tóth, I., Geraldes, C., Tircsó, G.: Complexes of Bifunctional DO3A-N-(alpha-amino)propinate Ligands with Mg(II), Ca(II), Cu(II), Zn(II), and Lanthanide(III) Ions: Thermodynamic Stability, Formation and Dissociation Kinetics, and Solution Dynamic NMR Studies.
Molecules. 26 (16), 1-26, 2021.

Kálmán, F., Nagy, V., Uzal, -., Pérez-Lourido, P., Esteban-Gómez, D., Garda, Z., Póta, K., Mezei, R., Pallier, A., Tóth, É., Platas-Iglesias, C., Tircsó, G.: Expanding the Ligand Classes Used for Mn(II) Complexation: Oxa-aza Macrocycles Make the Difference.
Molecules. 26 (6), 1-20, 2021.

Molnár, E., Lihi, N., Gál, G., De, S., Bombicz, P., Bányai, I., Szikra, D., Dénes, E., Tircsó, G., Tóth, I., Kálmán, F.: Exploring Cyclic Aminopolycarboxylate Ligands for Sb(III) Complexation: PCTA and Its Derivatives as a Promising Solution.
Inorg. Chem. 60 (18), 14253-14262, 2021.

Tircsó, G., Molnár, E., Csupász, T., Garda, Z., Botár, R., Kálmán, F., Kovács, Z., Brücher, E., Tóth, I.: Gadolinium(III)-Based Contrast Agents for Magnetic Resonance Imaging. A Re-Appraisal.
In: Metal Ions in Bio-Imaging Techniques. Ed.: Astrid Sigel, Eva Freisinger and Roland K.O. Sigel, De Gruyter, Berlin, 39-70, 2021, (Metal Ions in Life Sciences, ISSN 1559-0836 ; 22) ISBN: 9783110685701

Nizou, G., Molnár, E., Hamon, N., Kálmán, F., Fougère, O., Rousseaux, O., Esteban-Gómez, D., Platas-Iglesias, C., Beyler, M., Tircsó, G., Tripier, R.: Pyclen-Based Ligands Bearing Pendant Picolinate Arms for Gadolinium Complexation.
Inorg. Chem. 60 (4), 2390-2405, 2021.

Csupász, T., Lihi, N., Fekete, Z., Nagy, A., Botár, R., Forgács, V., Szikra, D., Tircsó, G., Kálmán, F.: Új típusú Cu(II)-komplexek radioteranosztikai alkalmazásokhoz.
In: 54. Komplexkémiai Kollokvium : az MKE Komplexkémiai Szakcsoportjának és az MTA Koordinációs Kémiai Munkabizottságának a rendezvénye, Magyar Kémikusok Egyesülete, Budapest, E31, 2021.

Póta, K., Molnár, E., Kálmán, F., Freire, D., Tircsó, G., Green, K.: Manganese complex of a rigidified 15-membered macrocycle: A comprehensive study.
Inorg. Chem. 59 (16), 11366-11376, 2020.

Kálmán, F., Nagy, V., Váradi, B., Garda, Z., Molnár, E., Trencsényi, G., Kiss, J., Même, S., Même, W., Tóth, É., Tircsó, G.: Mn(II)-based MRI contrast agent candidate for vascular imaging.
J. Med. Chem. 63 (11), 6057-6065, 2020.

Botár, R., Molnár, E., Trencsényi, G., Kiss, J., Kálmán, F., Tircsó, G.: Stable and inert Mn(II)-based and pH responsive contrast agents.
J. Am. Chem. Soc. 142 (4), 1662-1666, 2020.

Garda, Z., Nagy, V., Rodríguez-Rodríguez, A., Pujales, -., Patinec, V., Angelovski, G., Tóth, É., Kálmán, F., Esteban-Gómez, D., Tripier, R., Platas-Iglesias, C., Tircsó, G.: Unexpected Trends in the Stability and Dissociation Kinetics of Lanthanide(III) Complexes with Cyclen-Based Ligands across the Lanthanide Series.
Inorg. Chem. 59 (12), 8184-8195, 2020.

Le Fur, M., Molnár, E., Beyler, M., Kálmán, F., Fougère, O., Esteban-Gómez, D., Rousseaux, O., Tripier, R., Tircsó, G., Platas-Iglesias, C.: A Coordination Chemistry Approach to Fine-Tune the Physicochemical Parameters of Lanthanide Complexes Relevant to Medical Applications.
Chem.-Eur. J. 24 (13), 3127-3131, 2018.

Gündüz, S., Vibhute, S., Botár, R., Kálmán, F., Tóth, I., Tircsó, G., Regueiro-Figueroa, M., Esteban-Gómez, D., Platas-Iglesias, C., Angelovski, G.: Coordination Properties of GdDO3A-Based Model Compounds of Bioresponsive MRI Contrast Agents.
Inorg. Chem. 57 (10), 5973-5986, 2018.

Garda, Z., Molnár, E., Kálmán, F., Botár, R., Nagy, V., Baranyai, Z., Brücher, E., Kovács, Z., Tóth, I., Tircsó, G.: Effect of the Nature of Donor Atoms on the Thermodynamic, Kinetic and Relaxation Properties of Mn(II) Complexes Formed With Some Trisubstituted 12-Membered Macrocyclic Ligands.
Front. Chem. 6 1-14, 2018.

Laine, S., Bonnet, C., Kálmán, F., Garda, Z., Pallier, A., Caillé, F., Suzenet, F., Tircsó, G., Tóth, É.: Mn complexes of open-chain ligands with a pyridine backbone: less donor atoms lead to higher kinetic inertness.
New J. Chem. 42 (10), 8012-8020, 2018.

Molnár, E., Váradi, B., Garda, Z., Botár, R., Kálmán, F., Tóth, É., Tóth, I., Brücher, E., Tircsó, G.: Remarkable differences and similarities between the isomeric Mn(II)-cis- and trans-1,2-diaminocyclohexane-N,N,N',N'-tetraacetate complexes.
Inorg. Chim. Acta. 472 (1), 254-263, 2018.

Wurzer, A., Vágner, A., Horváth, D., Fellegi, F., Wester, H., Kálmán, F., Notni, J.: Synthesis of Symmetrical Tetrameric Conjugates of the Radiolanthanide Chelator DOTPI for Application in Endoradiotherapy by Means of Click Chemistry.
Front. Chem. 6 1-11, 2018.

Póta, K., Garda, Z., Kálmán, F., Barriada, J., Esteban-Gómez, D., Platas-Iglesias, C., Tóth, I., Brücher, E., Tircsó, G.: Taking the next step toward inert Mn2+ complexes of open-chain ligands: the case of the rigid PhDTA ligand.
New J. Chem. 42 (10), 8001-8011, 2018.

Do, Q., Ratnakar, J., Kovács, Z., Tircsó, G., Kálmán, F., Baranyai, Z., Brücher, E., Tóth, I.: General Synthetic and Physical Methods.
In: Contrast Agents for MRI: Experimental Methods. Ed.: Valérie C Pierre, Matthew J Allen, Royal Society of Chemistry, London, 1-120, 2017. ISBN: 9781782624479

Vanasschen, C., Molnár, E., Tircsó, G., Kálmán, F., Tóth, É., Brandt, M., Coenen, H., Neumaier, B.: Novel CDTA-based, Bifunctional Chelators for Stable and Inert Mn Complexation: Synthesis and Physicochemical Characterization.
Inorg. Chem. 56 (14), 7746-7760, 2017.

Tircsó, G., Brücher, E., Baranyai, Z., Kálmán, F., Tóth, I.: Nyíltláncú és makrociklusos aminokarboxilát ligandumok szintézise és fémkomplexeik vizsgálata: koordinációs kémia az orvosi képalkotás szolgálatában.
MKF. 123 (2), 82-93, 2017.

Tircsó, G., Regueiro-Figueroa, M., Nagy, V., Garda, Z., Garai, T., Kálmán, F., Esteban-Gómez, D., Tóth, É., Platas-Iglesias, C.: Approaching the Kinetic Inertness of Macrocyclic Gadolinium(III)-Based MRI Contrast Agents with Highly Rigid Open-Chain Derivatives.
Chem.-Eur. J. 22 (3), 896-901, 2016.

Rodríguez-Rodríguez, A., Regueiro-Figueroa, M., Esteban-Gómez, D., Tripier, R., Tircsó, G., Kálmán, F., Bényei, A., Tóth, I., Blas, A., Rodríguez-Blas, T., Platas-Iglesias, C.: Complexation of Ln3+ Ions with Cyclam Dipicolinates: A Small Bridge that Makes Huge Differences in Structure, Equilibrium, and Kinetic Properties.
Inorg. Chem. 55 (5), 2227-2239, 2016.

Baranyai, Z., Garda, Z., Kálmán, F., Krusper, L., Tircsó, G., Tóth, I., Ghiani, S., Maiocchi, A.: Ethylenediaminetetraacetic acid bis(amide) derivatives and their respective complexes with Mn(II) ion for use as MRI contrast agent.
[szabadalom]

Baranyai, Z., Garda, Z., Kálmán, F., Krusper, L., Tircsó, G., Tóth, I.: New substituted ethylene-diamine-tetraacetic-acid-bis(amide) derivatives and use thereof as ligand containing Mn(II) of MRI contrast agent.
[szabadalom]

Garda, Z., Forgács, A., Do, Q., Kálmán, F., Timári, S., Baranyai, Z., Tei, L., Tóth, I., Kovács, Z., Tircsó, G.: Physico-chemical properties of MnII complexes formed with cis- and trans-DO2A: thermodynamic, electrochemical and kinetic studies.
J. Inorg. Biochem. 163 206-213, 2016.

Farkas, E., Fodor, T., Kálmán, F., Tircsó, G., Tóth, I.: Equilibrium and dissociation kinetics of the [Al(NOTA)] complex (NOTA=1,4,7-triazacyclononane-1,4,7-triacetate).
React. Kinet. Mech. Catal. 116 (1), 19-33, 2015.

Kálmán, F., Végh, A., Regueiro-Figueroa, M., Tóth, É., Platas-Iglesias, C., Tircsó, G.: H4octapa: Highly Stable Complexation of Lanthanide(III) Ions and Copper(II).
Inorg. Chem. 54 (5), 2345-2356, 2015.

Molnár, E., Camus, N., Patinec, V., Rolla, G., Botta, M., Tircsó, G., Kálmán, F., Fodor, T., Tripier, R., Platas-Iglesias, C.: Picolinate-Containing Macrocyclic Mn(II) Complexes as Potential MRI Contrast Agents.
Inorg. Chem. 53 (10), 5136-5149, 2014.

Garda, Z., Fodor, T., Molnár, E., Botár, R., Kálmán, F., Tóth, I., Tircsó, G., Kovács, Z.: Thermodynamic and kinetic properties of Mn2+cyclododecane derivative complexes: fine-tuning by the nature of donor atoms.
J. Biol. Inorg. Chem. 19 (S1), S686, 2014.

Tircsó, G., Kálmán, F., Baranyai, Z., Forgács, A., Molnár, E., Tóth, I., Kovács, Z.: Tuning the physico-chemical properties of the Ln3+complexes formed with some cyclododecane derivatives by careful ligand design.
J. Biol. Inorg. Chem. 19 (S1), S691, 2014.

Placidi, M., Botta, M., Kálmán, F., Hagberg, G., Baranyai, Z., Krenzer, A., Rogerson, A., Tóth, I., Logothetis, N., Angelovski, G.: Aryl-Phosphonate Lanthanide Complexes and Their Fluorinated Derivatives: Investigation of Their Unusual Relaxometric Behavior and Potential Application as Dual Frequency 1H/19F MRI Probes.
Chem.-Eur. J. 19 (35), 11644-11660, 2013.

Tircsó, G., Garda, Z., Kálmán, F., Baranyai, Z., Pócsi, I., Balla, G., Tóth, I.: Lanthanide(III) complexes of some natural siderophores: a thermodynamic, kinetic and relaxometric study.
J. Inorg. Biochem. 127 53-61, 2013.

Baranyai, Z., Tei, L., Giovenzana, G., Kálmán, F., Botta, M.: Equilibrium and NMR Relaxometric Studies on the s-Triazine-Based Heptadentate Ligand PTDITA Showing High Selectivity for Gd3+ Ions.
Inorg. Chem. 51 (4), 2597-2607, 2012.

Kálmán, F., Tircsó, G.: Kinetic Inertness of the Mn Complexes Formed with AAZTA and Some Open-Chain EDTA Derivatives.
Inorg. Chem. 51 (19), 10065-10067, 2012.

Tircsó, G., Kálmán, F., Pál, R., Bányai, I., Varga, T., Király, R., Lázár, I., Québatte, L., Merbach, A., Tóth, É., Brücher, E.: Lanthanide Complexes Formed with the Tri- and Tetraacetate Derivatives of Bis(aminomethyl)phosphinic Acid: Equilibrium, Kinetic and NMR Spectroscopic Studies.
Eur. J. Inorg. Chem. 12 2062-2073, 2012.

Geninatti-Crich, S., Cutrin, J., Lanzardo, S., Kálmán, F., Kálmán-Szabó, I., Lago, N., Iolascon, A., Aime, S.: Mn-loaded apoferritin: a highly sensitive MRI imaging probe for the detection and characterization of hepatocarcinoma lesions in a transgenic mouse model.
Contrast. Media Mol. Imaging. 7 (3), 281-288, 2012.

Szabó, I., Geninatti-Crich, S., Alberti, D., Kálmán, F., Aime, S.: Mn loaded apoferritin as an MRI sensor of melanin formation in melanoma cells.
Chem. Commun. 48 2436-2438, 2012.

Kálmán-Szabó, I., Crich, S., Alberti, D., Kálmán, F., Aime, S.: Mn loaded apoferritin as an MRI sensor of melanin formation in melanoma cells.
Chem. Commun. 48 (18), 2436-2438, 2012.

Tei, L., Baranyai, Z., Cassino, C., Fekete, M., Kálmán, F., Botta, M.: Solution properties of the Ln(III) complexes of a novel octadentate chelator with rigidified iminodiacetate arms.
Dalton Trans. 41 12797-12806, 2012.

Rojas-Quijano, F., Tircsó, G., Tircsóné Benyó, E., Baranyai, Z., Tran, -., Kálmán, F., Gulaka, P., Kodibagkar, V., Aime, S., Kovács, Z., Sherry, A.: Synthesis and Characterization of a Hypoxia-Sensitive MRI Probe.
Chem.-Eur. J. 18 (31), 9669-9676, 2012.

Tei, L., Gugliotta, G., Fekete, M., Kálmán, F., Botta, M.: Mn(ii) complexes of novel hexadentate AAZTA-like chelators: a solution thermodynamics and relaxometric study.
Dalton Trans. 40 (9), 2025-2032, 2011.

Gianolio, E., Ramalingam, K., Song, B., Kálmán, F., Aime, S., Swenson, R.: Improving the relaxivity by dimerizing Gd-AAZTA: Insights for enhancing the sensitivity of MRI contrast agents.
Inorg. Chem. Commun. 13 (5), 663-665, 2010.

Kálmán, F., Geninatti-Crich, S., Aime, S.: Reduction/Dissolution of a beta-MnOOH Nanophase in the Ferritin Cavity To Yield a Highly Sensitive, Biologically Compatible Magnetic Resonance Imaging Agent.
Angew. Chem., Int. ed. Eng. 49 (3), 612-615, 2010.

Rojas-Quijano, F., Tircsóné Benyó, E., Tircsó, G., Kálmán, F., Baranyai, Z., Aime, S., Sherry, A., Kovács, Z.: Lanthanide(III) Complexes of Tris(amide) PCTA Derivatives as Potential Bimodal Magnetic Resonance and Optical Imaging Agents.
Chem.-A Eur. J. 15 (47), 13188-13200, 2009.

Kálmán, F., Király, R., Brücher, E.: Stability constants and dissociation rates of the EDTMP complexes of Samarium(III) and Yttrium(III).
Eur. J. Inorg. Chem. 30 4719-4727, 2008.

Kálmán, F., Baranyai, Z., Tóth, I., Bányai, I., Király, R., Brücher, E., Aime, S., Sun, X., Sherry, A., Kovács, Z.: Synthesis, potentiometric, kinetic, and NMR studies of 1,4,7,10-tetraazacyclododecane-1,7-bis(acetic acid)-4,10-bis(methylenephosphonic acid) (DO2A2P) and its complexes with Ca(II), Cu(II), Zn(II) and lanthanide(III) ions.
Inorg. Chem. 47 (9), 3851-3862, 2008.

Kálmán, F., Woods, M., Caravan, P., Jurek, P., Spiller, M., Tircsó, G., Király, R., Brücher, E., Sherry, A.: Potentiometric and relaxometric properties of a gadolinium-based MRI contrast agent for sensing tissue pH.
Inorg. Chem. 46 (13), 5260-5270, 2007.

Kotek, J., Kálmán, F., Hermann, P., Brücher, E., Binnemans, K., Lukeš, I.: Study of thermodynamic and kinetic stability of transition metal and lanthanide complexes of DTPA analogues with a phosphorus acid pendant arm.
Eur. J. Inorg. Chem. 2006 (10), 1976-1986, 2006.

Trokowski, R., Ren, J., Kálmán, F., Sherry, A.: Selective sensing of zinc ions with a PARACEST contrast agent.
Angew. Chem.-Int. Edit. 44 (42), 6920-6923, 2005.